Both the choices are decent so you can choose either. But, as I don't know exactly which branch of DSU are you asking about; but if you are talking about DSU (Kumar swami layout) then go for it; and if not NHCE is better.
And let me clear that, 100% placements mean there are no specifications of package you will be given. You might get a company to work with a 1 LPA salary or a 12 LPA salary depends on your caliber and knowledge.