Question:

For the reaction, $H_{2} + I_{2} {\rightleftharpoons} 2HI, K= 47.6.$ If the initial number of moles of each reactant and product is 1 mole then at equilibrium

Updated On: Nov 28, 2022
  • $\left[I_{2}\right]=\left[H_{2}\right], \left[I_{2}\right] > \left[HI\right]$
  • $({\frac{x^3}{9}})$
  • \(\left[I_{2}\right]>\left[H_{2}\right], \left[I_{2}\right] = \left[HI\right]\)

  • $\omega\propto\,n^{\frac{1}{3}}$
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The Correct Option is B

Solution and Explanation

For the given reaction, $K = \frac{\left[HI\right]^{2}}{\left[H_{2}\right]\left[I_{2}\right]}$ As 1 mole of H$_2$ reacts with 1 mole of I$_2$, even at equilibrium, $[H_2] = [I_2]$ Hence, $K = \frac{\left[HI\right]^{2}}{\left[I_{2}\right]^{2}}\quad$ or$\quad\sqrt{K}=\frac{\left[HI\right]}{\left[I_{2}\right]}=\sqrt{47.6}$ i.e., $\left[HI\right]>\left[I_{2}\right]$
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Concepts Used:

Acids and Bases

$P = - \frac{xx^T}{x^Tx}$Acid is any hydrogen-containing substance that is capable of donating a proton (hydrogen ion) to another substance. Base is an ion or molecule capable of accepting a hydrogen ion from acid. 

Physical Properties of Acids and Bases

Physical PropertiesACIDSBASES
TasteSourBitter
Colour on Litmus paper Turns blue litmus redTurns red litmus blue
Ions produced on dissociationH+OH-
pH<7 (less than 7)>7 (more than 7)
Strong acidsHCl, HNO3, H2SO4NaOH, KOH
Weak AcidsCH3COOH, H3PO4, H2CO3NH4OH

Chemical Properties of Acids and Bases

Type of ReactionAcidBases
Reaction with Metals

Acid + Metal → Salt + Hydrogen gas (H2)

E.g.,

Zn(s)+ dil. H2SO4 → ZnSO(Zinc Sulphate) + H2

Base + Metal → Salt + Hydrogen gas (H2)

E.g.,

2NaOH +Zn → Na2ZnO2 (Sodium zincate) + H2

Reaction with hydrogen carbonates (bicarbonate) and carbonates

Metal carbonate/Metal hydrogen carbonate + Acid → Salt + Carbon dioxide + Water

E.g., HCl+NaOH → NaCl+ H2O

2. Na2CO3+ 2 HCl(aq) →2NaCl(aq)+ H2O(l) + CO2(g)

3. Na2CO3+ 2H2SO4(aq) →2Na2SO4(aq)+ H2O(l) + CO2(g)

4. NaHCO3+ HCl → NaCl+ H2O+ CO2

Base+ Carbonate/ bicarbonate → No reaction
Neutralisation Reaction

Base + Acid → Salt + Water

E.g., NaOH(aq) + HCl(aq) → NaCl(aq) + H2O(l)

Base + Acid → Salt + Water

E.g., CaO+ HCl (l) → CaCl2 (aq)+ H2O (l)

Reaction with Oxides

Metal oxide + Acid → Salt + Water

E.g., CaO+ HCl (l) → CaCl2 (aq)+ H2O (l)

Non- Metallic oxide + Base → Salt + Water

E.g., Ca(OH)2+ CO2 → CaCO3+ H2O

Dissolution in Water

Acid gives H+ ions in water.

E.g., HCl → H+ + Cl-

HCl + H2O → H3O+ + Cl–

Base gives OH- ions in water.

Read more on Acids, Bases and Salts