According to my friends from Kirori Mal College, with a percentage of 96.25, you will have a decent chance of getting admission in Political Science (Hons). However, it also depends on your caste.
In 2021, the required cutoff for Political Science (Hons) was 98.75-99.25 for the General category. With your course, you can expect to get into tier 2 colleges like KMC, Venky, SGTB Khalsa, Ramjas, Gargi, JMC, etc.